Named for its sandwich-layered construction, PEX uses cross-linked polyethylene as the outside layer, aluminum as the middle layer, and another layer of poly on the inside. This piping is approved in major plumbing codes, and it's had a successful 30-year track record in Europe. It's a little more expensive than rigid copper piping, but the advantages outweigh the extra cost, because you can save money by doing the job yourself.
PEX is sold at all major hardware stores, where it's usually sold as water supply piping and infloor radiant-heat lines. When you buy it, make sure the tubing is stamped with 'NSF-61' or 'NSF pw' (for potable water), which distinguishes it from the PEX that is used only for infloor radiant heating applications.
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